SRF2021 - List of Authors (Antoine, C.Z.)

Paper	Title	Page
FROFDV06	Synthesis of Nb and Alternative Superconducting Film to Nb for SRF Cavity as Single Layer	893
	R. Valizadeh, P. Goudket, A.N. Hannah, O.B. Malyshev STFC/DL/ASTeC, Daresbury, Warrington, Cheshire, United Kingdom C.Z. Antoine CEA-DRF-IRFU, France C.Z. Antoine CEA-IRFU, Gif-sur-Yvette, France E. Chyhyrynets, C. Pira INFN/LNL, Legnaro (PD), Italy P. Goudket, O.B. Malyshev, D.J. Seal, B.S. Sian, D.A. Turner Cockcroft Institute, Warrington, Cheshire, United Kingdom O. Kugeler, D.B. Tikhonov HZB, Berlin, Germany S.B. Leith, A.Ö. Sezgin, M. Vogel University Siegen, Siegen, Germany A. Medvids, P. Onufrijevs Riga Technical University, Riga, Latvia D.J. Seal, B.S. Sian, D.A. Turner Lancaster University, Lancaster, United Kingdom G.B.G. Stenning STFC/RAL/ISIS, Chilton, Didcot, Oxon, United Kingdom A. Sublet, G. Vandoni, L. Vega Cid, W. Venturini Delsolaro, P. Vidal García CERN, Meyrin, Switzerland
	"Bulk niobium (Nb) has been the material of choice for superconducting RF (SRF) cavities but for further improvement in cavity RF performance, one may have to turn to films of Nb and to other superconducting materials deposited on copper as thermal and mechanical support. Other materials known as A15, such as Nb₃Sn or V₃Si and B1 such as NbTiN and NbN are much easier to synthesise in thin films rather than being made as bulk cavity. The potential benefits of using materials other than Nb would be a higher Tc, a potentially higher critical held Hc, leading to potentially significant cryogenics cost reduction if the cavity operation temperature is 4.2 K or higher. We report on optimising deposition parameters and effect of substrate treatment prior to deposition for successful synthesising of Nb and the alternative superconducting thin film with high superconducting properties (Tc and Hsh) on flat substrates and QPR samples in single layer. The DC and RF SC properties have been tested using PPMS and QPR measurements. This work is part of the H2020 ARIES collaboration. We further report on preparation of RF cavities employing these alternative material for future cavity production."
DOI •	reference for this paper ※ doi:10.18429/JACoW-SRF2021-FROFDV06
About •	Received ※ 21 June 2021 — Accepted ※ 05 January 2022 — Issue date ※ 28 April 2022
Cite •	reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

SUPTEV016	Samples for 3rd Harmonic Magnetometry Assessment of NbTiN-Based SIS Structures	164
	D.R. Beverstock, J.R. Delayen, I.H. Senevirathne, J.K. Spradlin, A-M. Valente-Feliciano JLab, Newport News, Virginia, USA C.Z. Antoine CEA-IRFU, Gif-sur-Yvette, France J.R. Delayen, I.H. Senevirathne ODU, Norfolk, Virginia, USA D. Manos The College of William and Mary, Williamsburg, Virginia, USA
	Funding: Authored by Jefferson Science Associates, LLC under U.S. DOE Contract No. DE-AC05-06OR23177. NSF Grants PHY-1734075 and PHY-1416051, and DOE Awards DE-SC0010081 and DE-SC0019399. In the quest for alternative superconducting materials to bring accelerator cavity performance beyond the bulk niobium (Nb) intrinsic limits, a promising concept uses superconductor-insulator-superconductor (SIS) thin film structures that allows magnetic flux shielding in accelerator cavities to higher fields [1]. Candidate materials for such structures are NbTiN as the superconductor and AlN as the insulator. We have demonstrated high quality NbTiN and AlN deposited by reactive DC magnetron sputtering (DCMS), both for individual layers and multilayers. Interface quality has been assessed for bilayer stacks with 250 nm NbTiN layers and AlN thicknesses from 30 nm down to1 nm. These SIS structures show continued sharp interfaces with total average roughness under 2 nm. The Hfp enhancement of the films will be examined with a 3rd harmonic magnetometry. The system is being designed and built in a continuing collaboration with CEA Saclay. It can measure 25 to 50 mm samples on a temperature controlled stage. This contribution presents an overview of the design of the 3rd harmonic magnetometer and the material properties assessment of standalone films and multilayer nanostructures. [1] A. Gurevich, Applied Physics Letters, vol. 88, p. 012511, 2006.
DOI •	reference for this paper ※ doi:10.18429/JACoW-SRF2021-SUPTEV016
About •	Received ※ 22 June 2021 — Accepted ※ 10 November 2021 — Issue date ※ 16 May 2022
Cite •	reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

MOPFDV001	Investigation of an Alternative Path for SRF Cavity Fabrication and Surface Processing	319
	O. Hryhorenko, D. Longuevergne Université Paris-Saclay, CNRS/IN2P3, IJCLab, Orsay, France C.Z. Antoine CEA-IRFU, Gif-sur-Yvette, France F. Brisset ICMMO, Orsay, France T. Dohmae KEK, Ibaraki, Japan
	The preparation of SRF cavities includes a lengthy, costly, and safety issued electrochemical polishing (EP or BCP) step to remove the damaged layer coming from the cavity fabrication. We have shown that most of the damage layer is originated from the rolling process during the preparation of the sheet material, while subsequent deep drawing tends to leave only µm thick damage layer. We propose a 2-steps mechanical process that allows us to easily get rid of the thick damage layer on the sheets before cavity forming. The process has been established on samples and extended to large disks ready for 1.3 GHz half-cell forming. The polished sheets will be then sent to KEK for half-cell forming and subsequent surface and material analysis before proceeding to half-cell welding. Former studies on the sample demonstrated that damages induced by forming can successfully be removed by recrystallization and less than 10 µm final chemistry.
	Poster MOPFDV001 [2.309 MB]
DOI •	reference for this paper ※ doi:10.18429/JACoW-SRF2021-MOPFDV001
About •	Received ※ 25 June 2021 — Revised ※ 11 July 2021 — Accepted ※ 21 August 2021 — Issue date ※ 15 May 2022
Cite •	reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

WEPFDV007	Main Highlights of ARIES WP15 Collaboration	571
	O.B. Malyshev, P. Goudket, R. Valizadeh STFC/DL/ASTeC, Daresbury, Warrington, Cheshire, United Kingdom C.Z. Antoine CEA-IRFU, Gif-sur-Yvette, France O. Azzolini, E. Chyhyrynets, G. Keppel, C. Pira, F. Stivanello INFN/LNL, Legnaro (PD), Italy G. Burt, D.J. Seal, D.A. Turner Cockcroft Institute, Lancaster University, Lancaster, United Kingdom G. Burt, B.S. Sian Lancaster University, Lancaster, United Kingdom O. Kugeler, D.B. Tikhonov HZB, Berlin, Germany S.B. Leith, A.Ö. Sezgin, M. Vogel University Siegen, Siegen, Germany A. Medvids, P. Onufrijevs Riga Technical University, Riga, Latvia R. Ries, E. Seiler Slovak Academy of Sciences, Institute of Electrical Engineering, Bratislava, Slovak Republic B.S. Sian Cockcroft Institute, Warrington, Cheshire, United Kingdom A. Sublet, G. Vandoni, L. Vega Cid, W. Venturini Delsolaro, P. Vidal García CERN, Meyrin, Switzerland D.A. Turner STFC/DL, Daresbury, Warrington, Cheshire, United Kingdom
	Funding: European Commission’s ARIES collaboration H2020 Research and Innovation Programme under Grant Agreement no. 730871 An international collaboration of research teams from CEA (France), CERN (Switzerland), INFN/LNL (Italy), HZB and USI (Germany), IEE (Slovakia), RTU (Latvia) and STFC/DL (UK), are working together on better understanding of how to improve the properties of superconducting thin films (ScTF) for RF cavities. The collaboration has been formed as WP15 in the H2020 ARIES project funded by EC. The systematic study of ScTF covers: Cu substrate polishing with different techniques (EP, SUBU, EP+SUBU, tumbling, laser), Nb, NbN, Nb₃Sn and SIS film deposition and characterisation, Laser post deposition treatments, DC magnetisation characterisation, application of all obtained knowledge on polishing, deposition and characterisation, Laser post deposition treatments, DC magnetisation characterisation, application to the QPR samples for testing the films at RF conditions. The preparation, deposition and characterisation of each sample involves 3-5 partners enhancing the capability of each other and resulting in a more complete analysis of each film. The talk will give an overview of the collaborative research and will be an introduction to the detailed talks given by the team members.
	Poster WEPFDV007 [2.013 MB]
DOI •	reference for this paper ※ doi:10.18429/JACoW-SRF2021-WEPFDV007
About •	Received ※ 19 June 2021 — Accepted ※ 12 February 2022 — Issue date ※ 10 April 2022
Cite •	reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

FROFDV07	Material Engineering of ALD- Deposited Multilayer to Improve the Superconducting Performances of RF Cavities Under Intense RF Fields
	Y. Kalboussi CEA, DES-ISAS-DM2S, Université Paris-Saclay, Gif-sur-Yvette, France C.Z. Antoine, B. Delatte CEA-IRFU, Gif-sur-Yvette, France S. Bira, D. Longuevergne Université Paris-Saclay, CNRS/IN2P3, IJCLab, Orsay, France D. Dragoe ICMMO, Orsay, France J. Leroy CEA/DRF/IRAMIS/SIS2M, Gif sur Yvette, France Th. Proslier CEA-DRF-IRFU, France S. Tusseau-Nenez Ecole Polytechnique, Palaiseau, France
	We are exploring an original approach to improve the performance of bulk Niobium RF cavities through surface engineering with ALD superconducting multilayer capable of screening efficiently the magnetic fields and therefore inhibiting vortices penetration in Niobium cavities. As a first step for the multilayer, we aim at replacing the deleterious niobium native oxide by a clean interface between an insulator synthesized by ALD (Al₂O₃, Y2O3 and MgO) and the Niobium metal. To that end I will present the results obtained on both flat niobium samples and 1.3 GHz elliptical cavities. Our study shows that ALD deposited films are a good diffusion barrier, resist to thermal treatments and reduce significantly the presence of the niobium native oxide on the surface. Low SEY material such as TiN was also deposited on top of the insulator film to reduce multipacting phenomena. RF test on ALD coated cavities shows already a slight improvement of the superconducting performances. In parallel we started synthesizing superconducting NbTiN alloys by ALD. I will present preliminary results on the superconducting properties of NbTiN films grown on AlN by ALD with various compositions on Nbiobium.
Cite •	reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

Paper

Title

Page

Synthesis of Nb and Alternative Superconducting Film to Nb for SRF Cavity as Single Layer

893

R. Valizadeh, P. Goudket, A.N. Hannah, O.B. Malyshev
STFC/DL/ASTeC, Daresbury, Warrington, Cheshire, United Kingdom
C.Z. Antoine
CEA-DRF-IRFU, France
C.Z. Antoine
CEA-IRFU, Gif-sur-Yvette, France
E. Chyhyrynets, C. Pira
INFN/LNL, Legnaro (PD), Italy
P. Goudket, O.B. Malyshev, D.J. Seal, B.S. Sian, D.A. Turner
Cockcroft Institute, Warrington, Cheshire, United Kingdom
O. Kugeler, D.B. Tikhonov
HZB, Berlin, Germany
S.B. Leith, A.Ö. Sezgin, M. Vogel
University Siegen, Siegen, Germany
A. Medvids, P. Onufrijevs
Riga Technical University, Riga, Latvia
D.J. Seal, B.S. Sian, D.A. Turner
Lancaster University, Lancaster, United Kingdom
G.B.G. Stenning
STFC/RAL/ISIS, Chilton, Didcot, Oxon, United Kingdom
A. Sublet, G. Vandoni, L. Vega Cid, W. Venturini Delsolaro, P. Vidal García
CERN, Meyrin, Switzerland

"Bulk niobium (Nb) has been the material of choice for superconducting RF (SRF) cavities but for further improvement in cavity RF performance, one may have to turn to films of Nb and to other superconducting materials deposited on copper as thermal and mechanical support. Other materials known as A15, such as Nb₃Sn or V₃Si and B1 such as NbTiN and NbN are much easier to synthesise in thin films rather than being made as bulk cavity. The potential benefits of using materials other than Nb would be a higher Tc, a potentially higher critical held Hc, leading to potentially significant cryogenics cost reduction if the cavity operation temperature is 4.2 K or higher. We report on optimising deposition parameters and effect of substrate treatment prior to deposition for successful synthesising of Nb and the alternative superconducting thin film with high superconducting properties (Tc and Hsh) on flat substrates and QPR samples in single layer. The DC and RF SC properties have been tested using PPMS and QPR measurements. This work is part of the H2020 ARIES collaboration. We further report on preparation of RF cavities employing these alternative material for future cavity production."

DOI •

reference for this paper ※ doi:10.18429/JACoW-SRF2021-FROFDV06

About •

Received ※ 21 June 2021 — Accepted ※ 05 January 2022 — Issue date ※ 28 April 2022

Cite •

reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

SUPTEV016

Samples for 3rd Harmonic Magnetometry Assessment of NbTiN-Based SIS Structures

164

D.R. Beverstock, J.R. Delayen, I.H. Senevirathne, J.K. Spradlin, A-M. Valente-Feliciano
JLab, Newport News, Virginia, USA
C.Z. Antoine
CEA-IRFU, Gif-sur-Yvette, France
J.R. Delayen, I.H. Senevirathne
ODU, Norfolk, Virginia, USA
D. Manos
The College of William and Mary, Williamsburg, Virginia, USA

Funding: Authored by Jefferson Science Associates, LLC under U.S. DOE Contract No. DE-AC05-06OR23177. NSF Grants PHY-1734075 and PHY-1416051, and DOE Awards DE-SC0010081 and DE-SC0019399.
In the quest for alternative superconducting materials to bring accelerator cavity performance beyond the bulk niobium (Nb) intrinsic limits, a promising concept uses superconductor-insulator-superconductor (SIS) thin film structures that allows magnetic flux shielding in accelerator cavities to higher fields [1]. Candidate materials for such structures are NbTiN as the superconductor and AlN as the insulator. We have demonstrated high quality NbTiN and AlN deposited by reactive DC magnetron sputtering (DCMS), both for individual layers and multilayers. Interface quality has been assessed for bilayer stacks with 250 nm NbTiN layers and AlN thicknesses from 30 nm down to1 nm. These SIS structures show continued sharp interfaces with total average roughness under 2 nm. The Hfp enhancement of the films will be examined with a 3rd harmonic magnetometry. The system is being designed and built in a continuing collaboration with CEA Saclay. It can measure 25 to 50 mm samples on a temperature controlled stage. This contribution presents an overview of the design of the 3rd harmonic magnetometer and the material properties assessment of standalone films and multilayer nanostructures.
[1] A. Gurevich, Applied Physics Letters, vol. 88, p. 012511, 2006.

DOI •

reference for this paper ※ doi:10.18429/JACoW-SRF2021-SUPTEV016

About •

Received ※ 22 June 2021 — Accepted ※ 10 November 2021 — Issue date ※ 16 May 2022

Cite •

reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

MOPFDV001

Investigation of an Alternative Path for SRF Cavity Fabrication and Surface Processing

319

O. Hryhorenko, D. Longuevergne
Université Paris-Saclay, CNRS/IN2P3, IJCLab, Orsay, France
C.Z. Antoine
CEA-IRFU, Gif-sur-Yvette, France
F. Brisset
ICMMO, Orsay, France
T. Dohmae
KEK, Ibaraki, Japan

The preparation of SRF cavities includes a lengthy, costly, and safety issued electrochemical polishing (EP or BCP) step to remove the damaged layer coming from the cavity fabrication. We have shown that most of the damage layer is originated from the rolling process during the preparation of the sheet material, while subsequent deep drawing tends to leave only µm thick damage layer. We propose a 2-steps mechanical process that allows us to easily get rid of the thick damage layer on the sheets before cavity forming. The process has been established on samples and extended to large disks ready for 1.3 GHz half-cell forming. The polished sheets will be then sent to KEK for half-cell forming and subsequent surface and material analysis before proceeding to half-cell welding. Former studies on the sample demonstrated that damages induced by forming can successfully be removed by recrystallization and less than 10 µm final chemistry.

Poster MOPFDV001 [2.309 MB]

DOI •

reference for this paper ※ doi:10.18429/JACoW-SRF2021-MOPFDV001

About •

Received ※ 25 June 2021 — Revised ※ 11 July 2021 — Accepted ※ 21 August 2021 — Issue date ※ 15 May 2022

Cite •

reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

WEPFDV007

Main Highlights of ARIES WP15 Collaboration

571

O.B. Malyshev, P. Goudket, R. Valizadeh
STFC/DL/ASTeC, Daresbury, Warrington, Cheshire, United Kingdom
C.Z. Antoine
CEA-IRFU, Gif-sur-Yvette, France
O. Azzolini, E. Chyhyrynets, G. Keppel, C. Pira, F. Stivanello
INFN/LNL, Legnaro (PD), Italy
G. Burt, D.J. Seal, D.A. Turner
Cockcroft Institute, Lancaster University, Lancaster, United Kingdom
G. Burt, B.S. Sian
Lancaster University, Lancaster, United Kingdom
O. Kugeler, D.B. Tikhonov
HZB, Berlin, Germany
S.B. Leith, A.Ö. Sezgin, M. Vogel
University Siegen, Siegen, Germany
A. Medvids, P. Onufrijevs
Riga Technical University, Riga, Latvia
R. Ries, E. Seiler
Slovak Academy of Sciences, Institute of Electrical Engineering, Bratislava, Slovak Republic
B.S. Sian
Cockcroft Institute, Warrington, Cheshire, United Kingdom
A. Sublet, G. Vandoni, L. Vega Cid, W. Venturini Delsolaro, P. Vidal García
CERN, Meyrin, Switzerland
D.A. Turner
STFC/DL, Daresbury, Warrington, Cheshire, United Kingdom

Funding: European Commission’s ARIES collaboration H2020 Research and Innovation Programme under Grant Agreement no. 730871
An international collaboration of research teams from CEA (France), CERN (Switzerland), INFN/LNL (Italy), HZB and USI (Germany), IEE (Slovakia), RTU (Latvia) and STFC/DL (UK), are working together on better understanding of how to improve the properties of superconducting thin films (ScTF) for RF cavities. The collaboration has been formed as WP15 in the H2020 ARIES project funded by EC. The systematic study of ScTF covers: Cu substrate polishing with different techniques (EP, SUBU, EP+SUBU, tumbling, laser), Nb, NbN, Nb₃Sn and SIS film deposition and characterisation, Laser post deposition treatments, DC magnetisation characterisation, application of all obtained knowledge on polishing, deposition and characterisation, Laser post deposition treatments, DC magnetisation characterisation, application to the QPR samples for testing the films at RF conditions. The preparation, deposition and characterisation of each sample involves 3-5 partners enhancing the capability of each other and resulting in a more complete analysis of each film. The talk will give an overview of the collaborative research and will be an introduction to the detailed talks given by the team members.

Poster WEPFDV007 [2.013 MB]

DOI •

reference for this paper ※ doi:10.18429/JACoW-SRF2021-WEPFDV007

About •

Received ※ 19 June 2021 — Accepted ※ 12 February 2022 — Issue date ※ 10 April 2022

Cite •

reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

FROFDV07

Material Engineering of ALD- Deposited Multilayer to Improve the Superconducting Performances of RF Cavities Under Intense RF Fields

Y. Kalboussi
CEA, DES-ISAS-DM2S, Université Paris-Saclay, Gif-sur-Yvette, France
C.Z. Antoine, B. Delatte
CEA-IRFU, Gif-sur-Yvette, France
S. Bira, D. Longuevergne
Université Paris-Saclay, CNRS/IN2P3, IJCLab, Orsay, France
D. Dragoe
ICMMO, Orsay, France
J. Leroy
CEA/DRF/IRAMIS/SIS2M, Gif sur Yvette, France
Th. Proslier
CEA-DRF-IRFU, France
S. Tusseau-Nenez
Ecole Polytechnique, Palaiseau, France

We are exploring an original approach to improve the performance of bulk Niobium RF cavities through surface engineering with ALD superconducting multilayer capable of screening efficiently the magnetic fields and therefore inhibiting vortices penetration in Niobium cavities. As a first step for the multilayer, we aim at replacing the deleterious niobium native oxide by a clean interface between an insulator synthesized by ALD (Al₂O₃, Y2O3 and MgO) and the Niobium metal. To that end I will present the results obtained on both flat niobium samples and 1.3 GHz elliptical cavities. Our study shows that ALD deposited films are a good diffusion barrier, resist to thermal treatments and reduce significantly the presence of the niobium native oxide on the surface. Low SEY material such as TiN was also deposited on top of the insulator film to reduce multipacting phenomena. RF test on ALD coated cavities shows already a slight improvement of the superconducting performances. In parallel we started synthesizing superconducting NbTiN alloys by ALD. I will present preliminary results on the superconducting properties of NbTiN films grown on AlN by ALD with various compositions on Nbiobium.

Cite •

reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)