Author: Chattrapiban, N.
Paper Title Page
THPOMS039 Investigation on Intermolecular Interactions in Ionic Liquids Using Accelerator-based THz Transition Radiation 3053
 
  • P. Nanthanasit, S. Rimjaem
    Chiang Mai University, Chiang Mai, Thailand
  • N. Chattrapiban, P. Nimmanpipug, S. Rimjaem
    ThEP Center, Commission on Higher Education, Bangkok, Thailand
  • M. Jitvisate
    Suranaree University of Technology, Nakhon Ratchasima, Thailand
 
  Ionic liquids (ILs) are interesting material that can be used in many applications. Spectroscopic measurement using accelerator-based terahertz transition radiation (THz TR) is one of potential techniques to investigate their intermolecular interactions by observing the vibra-tional bands in the terahertz region due to TR’s excep-tional properties: coherent, broadband, and high intensi-ty. This work aims to study intermolecular interactions of ILs using the THz TR produced from an electron beam at the PBP-CMU Electron Linac Laboratory. The THz TR with the frequency range of 0.3-2.5 THz can be produced from electron beam of energy 10-25 MeV. This radiation is produced and transported to the experimental area, where it is used as the coherent and polarization selective light source for the Fourier transform infrared (FTIR) spectrometer. The absorption spectrum in the THz region of the ILs is then measured. In addition, to explain the experimental results deeply, theoretical calculations using the density functional theory are performed. In this contribution, we present the results from experiment and computational calculation that can be used together to describe the intermolecular interactions in ILs.  
DOI • reference for this paper ※ https://doi.org/10.18429/JACoW-IPAC2022-THPOMS039  
About • Received ※ 08 June 2022 — Accepted ※ 17 June 2022 — Issue date ※ 02 July 2022  
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